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Rh(III)‐catalyzed chelation‐assisted C8‐selective C−H alkenylation and alkylation of 1,2,3,4‐tretrahydroquinolines with styrenes and allylic alcohols have been realized. The cationic Rh(III) catalytic system in combination with a catalytic amount of copper acetate uses oxygen as the terminal oxidant and catalyzes the stereoselective C8‐alkenylation of 1,2,3,4‐tetrahydroquinolines with styrenes to...
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