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Crystalline porous organic salts (CPOSs), as an emerging class of porous organic materials, combining the uniform microporous system and distinct polarized channels, have become a highly evolving field of important current interest. The unique ionic bond of a CPOS endows the confined channels with high polarity, making CPOSs distinct from other organic frameworks. CPOSs show many fascinating properties,...
Crystalline porous organic salts (CPOSs) with a microporous polarized channel system offer a large array of fascinating properties including proton conductivity, CO2 diffusion, colossal negative linear compressibility, and molecular rotors, as reviewed by Li‐Hua Chen, Teng Ben, Bao‐Lian Su, and co‐workers in article number 2003270. The introduction of hierarchical porosity to CPOSs leads to new properties...
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