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Mit Hyperpolarisation, die zu einem Zielprotein gelenkt wird, ist es möglich, die Signale bestimmter Proteine von Hintergrundsignalen zu trennen. In der Zuschrift auf S. 10904 ff. zeigen M. Etzkorn et al., dass die dynamische Kernpolarisation durch einen mit einem Diradikal markierten Liganden zu einem Zielprotein gelenkt werden kann. Die resultierende Reduktion des Signalhintergrunds erleichtert...
Nuclear magnetic resonance (NMR) spectroscopy has the intrinsic capabilities to investigate proteins in native environments. In general, however, NMR relies on non‐natural protein purity and concentration to increase the desired signal over the background. We here report on the efficient and specific hyperpolarization of low amounts of a target protein in a large isotope‐labeled background by combining...
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