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Propyne/propylene (C3H4/C3H6) separation is an important but challenging industrial process to produce polymer‐grade C3H6 and recover high‐purity C3H4. Herein, we report an ultrastable TiF62− anion cross‐linked metal–organic framework (ZNU‐2) with precisely controlled pore size, shape and functionality for benchmark C3H4 storage (3.9/7.7 mmol g−1 at 0.01/1.0 bar and 298 K) and record high C3H4/C3H...
Propyne/propylene (C3H4/C3H6) separation is an important but challenging industrial process to produce polymer‐grade C3H6 and recover high‐purity C3H4. Herein, we report an ultrastable TiF62− anion cross‐linked metal–organic framework (ZNU‐2) with precisely controlled pore size, shape and functionality for benchmark C3H4 storage (3.9/7.7 mmol g−1 at 0.01/1.0 bar and 298 K) and record high C3H4/C3H...
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