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Chlorosilanes are versatile reagents in organic synthesis and material science. A mild pathway is now reported for the quantitative conversion of hydrosilanes to silyl chlorides under visible‐light irradiation using neutral eosin Y as a hydrogen‐atom‐transfer photocatalyst and dichloromethane as a chlorinating agent. Stepwise chlorination of di‐ and trihydrosilanes was achieved in a highly selective...
Die schwache Photolumineszenz von Silber‐Nanoclustern verhindert ihre breite Anwendung als lumineszenter Nanowerkstoff. In jüngerer Zeit haben Experimente jedoch gezeigt, dass eine Au‐Dotierung die Intensität der Photolumineszenz von Ag29‐Nanoclustern signifikant verstärken kann, wobei die molekularen und physikalischen Ursachen dieses Effekts noch unverstanden sind. Daher haben wir rechnerisch die...
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