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Axially chiral biaryl diols have achieved great success in asymmetric catalysis. By contrast, axially chiral biaryl amino alcohols are far less developed. Herein, we have rationally designed a versatile C1‐symmetric biaryl amino alcohol scaffold 1‐(1‐amino‐pyrrol‐2‐yl)naphthalen‐2‐ol (NPNOL) on the basis of axially chiral C2‐arylpyrrole framework. For its enantioselective synthesis, the chiral phosphoric...
Axially chiral biaryl diols have achieved great success in asymmetric catalysis. By contrast, axially chiral biaryl amino alcohols are far less developed. Herein, we have rationally designed a versatile C1‐symmetric biaryl amino alcohol scaffold 1‐(1‐amino‐pyrrol‐2‐yl)naphthalen‐2‐ol (NPNOL) on the basis of axially chiral C2‐arylpyrrole framework. For its enantioselective synthesis, the chiral phosphoric...
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