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The first manganese compound featuring a Mn–Mn bond, dimanganese decacarbonyl [Mn2(CO)10], was synthesized and first structurally characterized in the 1950s. Since then, the realm of Mn–Mn bonding species has significantly expanded. This chapter focuses on representative advancements of homobimetallic complexes with Mn‐Mn bonds published after 2000, while important historical aspects are included...
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