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We review here new developments in decreasing the catalyst loadings in palladium‐catalyzed C–C bond‐formation reactions to mol ppm or mol ppb levels. This decreases the cost of the catalyst and the toxicity of the reaction system, making the reaction more attractive to industry. The Heck reaction, Sonogashira reaction, Suzuki–Miyaura cross‐coupling reaction, other cross‐coupling reactions, and allylic...
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