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Poren als Reaktionsräume: 1,3‐Dipolare Huisgen‐Cycloadditionen von 2‐(Azidomethyl)triphenylen und Alkinen (siehe Schema) in einem porösen Koordinationsgerüst laufen als Einkristall‐Einkristall‐Umwandlungen ab. π‐Stapel und Nanoporen im Gerüst richten die Reaktionspartner so aus, dass das 1,4‐substituierte Isomer des 1,2,3‐Triazols selektiv als Produkt gebildet wird.
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