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Nichts dem Zufall überlassen: Über den schnellen und reversiblen Austausch zwischen „festen“ und „lockeren“ Ionenpaaren wurden die relativen Reaktivitäten von Ethen und 1‐Hexen oder Cyclopenten bei der lebenden Koordinations‐Kettentransfer‐Polymerisation moduliert. So konnten unterschiedliche Grade eines monodispersen Polyolefin‐Copolymers, z. B. die gezeigten Poly(ethen‐co‐1‐hexene), mit einem einzigen...
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