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Lebende supramolekulare Polymerisation liefert hoch geordnete lumineszierende Ketten aus molekularen PdII‐Einheiten. In ihrer Zuschrift auf S. 3143 berichten C.‐M. Che et al., wie die Energiebarriere (der Berg im Bildhintergrund) zwischen zwei aggregierten Zuständen überwunden werden kann, sodass molekulare PdII‐Aggregate aus einem kinetisch stabilen Dunkelzustand, in dem PdII‐Dimere durch Anionen...
Pincer PdII–isocyanide complexes are described that display intermolecular interactions and emissive 3MMLCT excited states in aggregation state(s) at room temperature. The intermolecular PdII−PdII and ligand–ligand interactions drive these complexes to undergo supramolecular polymerization in a living manner. Comprehensive spectroscopic studies reveal a pathway with a kinetic trap that can be modulated...
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