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POMs mit Protonenleitung. N. M. Khashab et al. berichten in ihrer Zuschrift auf S. 13230 über die Herstellung radförmiger {P8W48}‐Polyoxometallate (POMs), die große AlIII‐Oxo‐Cluster enthalten und erhöhte Protonenleitung aufweisen.
Complexes made by hosts that completely surround their guests provide a means to stabilize reactive chemical intermediates, transfer biologically active cargo to a diseased cell, and construct molecular‐scale devices. By the virtue of inorganic host–guest self‐assembly, nucleation processes in the cavity of a {P8W48}‐archetype phosphotungstate has afforded a nanoscale 16‐AlIII‐32‐oxo cluster and its...
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