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Two new sandwich-type heterometallic ZnII-LnIII clusters based on a methoxy substituted salicylamide Salen-like ligand, [Zn2Er3(HL)2(H2L)2(OH)2(NO3)3](NO3)2·2CH3OH (Zn2Er3), [Zn2Yb3(HL)2(H2L)2(OH)2 (NO3)3](NO3)2·2CH3OH (Zn2Yb3), H3L=1-(2-hydroxy-4-methoxy-benzamido)-2-(2-hydroxy-3-methoxy-benzylideneamino)-ethane, were prepared and structurally characterized. Single-crystal structure analyses reveal...
A new salicylamide Salen-like multidentate ligand, 1-(2-hydroxy-3-methoxy-benzamido)-2-(2-hydroxy-3-methoxy-benzylideneamino)-ethane (H3L), was synthesised and used to build up heterometallic magnetic clusters. As a result, four new highly thermal stable cyclic tetranuclear heterometallic clusters which were characterized by elemental analysis, X-ray diffraction, IR and TGA measurements, [M2Ln2L2(NO...
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