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The operational stability of polymer solar cells is a critical concern with respect to the thermodynamic relaxation of acceptor‐donor‐acceptor (A‐D‐A) or A‐DA'D‐A structured small‐molecule acceptors (SMAs) within their blends with polymer donors. Giant molecule acceptors (GMAs) bearing SMAs as subunits offer a solution to this issue, while their classical synthesis via the Stille coupling suffers...
The operational stability of polymer solar cells is a critical concern with respect to the thermodynamic relaxation of acceptor‐donor‐acceptor (A‐D‐A) or A‐DA'D‐A structured small‐molecule acceptors (SMAs) within their blends with polymer donors. Giant molecule acceptors (GMAs) bearing SMAs as subunits offer a solution to this issue, while their classical synthesis via the Stille coupling suffers...