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Two new noncentrosymmetric borophosphates, Li3Cs2Ba2B3P6O24, 1 and RbBaBP2O8, 2, have been synthesized via solid-state reactions at high temperature. The single crystal X-ray diffraction technique shows a cubic system, space group P213 (No 198) for 1 with a =12.8530(5) Å and tetragonal system I4̅2d (No 122) for 2 with a=7.2810(18) Å, c=14.330 (5) Å. The main structure motif attributes a 3D framework...
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