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Lithium (Li) metal electrode cannot endure elevated temperature (e.g., >200 °C) with the regular battery configuration due to its low melting point (180.5 °C) and high reactivity, which restricts its application in high‐temperature Li metal batteries for energy storage and causes safety concerns for regular ambient‐temperature Li metal batteries. Herein, this work reports a Li5B4/Li composite featuring...
In article number 2000952, Jun Lu, Yongming Sun, and co‐workers report an innovative Li/Li5B4 composite electrode featuring a 3D Li5B4 fibrillar framework filled with metallic Li. Benefiting from the effect of capillaries and the physical confinement of the 3D lithiophilic Li5B4 framework for metallic Li, the Li/Li5B4 composite electrode maintains its initial structure without leakage of liquid‐metallic...
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