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Hot‐electron‐driven chemical transformation (HEDCT) represents an emerging research area in utilizing photoresponsive nanoparticles to enable efficient solar‐to‐chemical conversion. The unique properties of quantum‐sized metal nanoparticles (QSMNPs) make them a class of photocatalysts that can generate hot electrons to drive surface chemical reactions with high quantum efficiency. Compared to the...
In article number 1802082, Yugang Sun and co‐workers highlight the efficient generation of hot electrons in quantum‐sized metal nanoparticles upon photo‐illumination. The hot electrons can be injected into the chemical bonds of the adsorbate molecules to activate the adsorbates followed by chemical transformation, resulting in the production of valuable chemicals.
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