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Low-molecular-weight organogels (LMOG) have been attracting a surge interest in fabricating soft materials. Although the finding of the gelator molecules has been developed from serendipity to objective design, the achievement of the gelator molecules still needs good design and tedious organic synthesis. In this paper, we proposed a simple and general mixing approach to get the organogel for nearly...
Achiral diacetylene 10,12-pentacosadinoic acid (PCDA) and a chiral low-molecular-weight organogelator could form co-gel in organic solvent and it could be polymerized in the presence of Zn(II) ion or in the corresponding xerogel under UV-irradiation. Optically active polydiacetylene (PDA) were subsequently obtained. Supramolecular chirality of PDA could be controlled by the chirality of gelators....
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