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The Gänseliesel showcases the scientific magic in Göttingen! Scientific magic on the α‐anomer of d‐glucosamine helps the targeted cleavage of C−N bonds in d‐glucosamine (α‐2° amine) from biobased resources and the conjunction of nitrogen in the synthesis of imidazo[1,5‐a]pyridines. This new approach expands the scope of readily accessible imidazo[1,5‐a]pyridines relative to existing state‐of‐the‐art...
The targeted cleavage of the C−N bonds of alkyl primary amines in sustainable compounds of biomass according to a metal‐free pathway and the conjunction of nitrogen in the synthesis of imidazo[1,5‐a]pyridines are still highly challenging. Despite tremendous progress in the synthesis of imidazo[1,5‐a]pyridines over the past decade, many of them can still not be efficiently prepared. Herein, we report...
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