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The intermolecular H‐bonding density heavily influences the gelation and rheological behavior of hydrogen‐bonded supramolecular polymer hydrogels, thus offering a delicate pathway to tailor their physicochemical properties for meeting a specific biomedical application. Herein, one methylene spacer between two amides in the side chain of N‐acryloyl glycinamide (NAGA) is introduced to generate a variant...
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