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An accurate thermodynamic model is proposed to predict the thermodynamic stability of methane hydrate in marine environments and methane concentration needed to form hydrate in the absence of gas phase. Taking into account the effect of capillary force and salinity on chemical potential of CH 4 and H 2 O, this study extends the Van der Waals–Platteeuw model and our approach to calculate...
A thermodynamic model for the solubility of carbon dioxide (CO 2 ) in pure water and in aqueous NaCl solutions for temperatures from 273 to 533 K, for pressures from 0 to 2000 bar, and for ionic strength from 0 to 4.3 m is presented. The model is based on a specific particle interaction theory for the liquid phase and a highly accurate equation of state for the vapor phase. With this specific...
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