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Heterometallic metal–organic frameworks (MOFs) are constructed from two or more kinds of metal ions, while still remaining their original topologies. Due to distinct reaction kinetics during MOF formation, partial distribution of different metals within a single MOF crystal can lead to sophisticated heterogeneous nanostructures. Here, this study reports an investigation of reaction kinetics for different...
In article number 1702049, Wenhan Guo, Ruqiang Zou and co‐workers develop a new strategy to synthesize metal–organic framework hybrid nanostructures by kinetic control. The growth kinetics of monometallic MOFs is revealed by in situ optical turbidity measurements, and accordingly bimetallic MOF nanoparticles with either solid‐solution, core‐shell or combined hybrid structures are purposively synthesized...
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