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A new method to prepare low melting point polyamide‐6 (LPA6) by complex reaction of calcium chloride (CaCl2) and polyamide‐6 (PA6) in a co‐rotating twin screw extruder was reported. We employed a new rheological method to study the crystallization behavior of PA6/CaCl2 complex and the mechanism of confined crystallization of PA6. Compared with differential scanning calorimetry (DSC), this method was...
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