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On page 6547 Do Kyung Kim, Jang Wook Choi and co‐workers describe a highly aligned and carbon‐encapsulated sulfur cathode synthesized with an AAO template that exhibits a high and long cycle life, and the best rate capability based on the complete encapsulation of sulfur (physical) and implementation of the monoclinic sulfur phase (chemical).
Monoclinic S8, an uncommon allotrope of sulfur at room temperature, can be formed when common orthorhombic S8 is heat‐treated under enclosed environments in nanometer dimensions. Monoclinic S8 prevents the formation of soluble polysulfides during battery operation, resulting in unprecedented cycling performance over 1000 cycles under the highest sulfur content to date.
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