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Large-amplitude ac voltammetry, where the applied voltage is a large-amplitude sinusoidal waveform superimposed onto a dc ramp, is a powerful method for investigating the reaction kinetics of surface-confined redox species. Here we consider the large-amplitude ac voltammetric current response of a quasi-reversible, ideal, surface-confined redox system, for which the redox reaction is described by...
Sinusoidal voltammetry, where the excitation voltage is a simple sine-wave, is a powerful technique for investigating the electrochemical behaviour of surface-confined redox species. Here we derive an analytical solution for the current response of an ideal, surface-confined, quasi-reversible redox system subjected to large-amplitude sinusoidal voltammetry. The solution is valid whenever the frequency...
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