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Toss the F: A new series of IrIII complexes functionalized with pyridyltriazolate chromophores and a tripodal dicyclometalated phosphite achieved highly efficient blue phosphorescence without employing any fluorine substituents. OLEDs with dopant [Ir(P C2)(bptz)(PMe2Ph)] (see structure; bptz=3‐tert‐butyl‐5‐(2‐pyridyl)‐1,2,4‐triazolate; P C2=dicyclometalated phosphite tripod) show outstanding performance.
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