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A series of chiral β-hydroxy amide ligands was synthesized via the reaction of benzoyl chloride and chiral amino alcohols derived from l-amino acid. Titanium(IV) complexes of these new β-hydroxy amide ligands were used for catalyzing the enantioselective addition of phenylacetylene to aldehydes. We found that the enantioselectivity of the reaction was strongly affected by the amount of titanium tetraisopropoxide...
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