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The complex formation of 5,10,15,20-tetraethyl-porphyrin and 2,3,7,8,12,13,17,18-octaethylporphyrin with iron(III) valinate and iron(II) guaninate and adeninate in DMSO was studied by spectrophotometry. Kinetic parameters were estimated and a possible reaction mechanism was proposed. The nature of the macrocyclic ligand and salt were shown to affect the reaction kinetics. The complex formation was...
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