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Benzamide‐derived organochalcogens (chalcogen=S, Se, and Te) have shown promising interest in biological and synthetic chemistry. Ebselen molecule derived from benzamide moiety is the most studied organoselenium. However, its heavier congener organotellurium is under‐explored. Here, an efficient copper‐catalyzed atom economical synthetic method has been developed to synthesize 2‐phenyl‐benzamide tellurenyl...