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The electron paramagnetic resonance (EPR) parameters and local structure of the octahedral [Cr(H2O)6]3+ complex for Cr3+ doped in GASH and AlCl3 · 6H2O crystals with trigonal symmetry have been studied on the basis of the 120 × 120 complete energy matrices, respectively. By simulating the EPR and optical spectra, the local structure distortion parameters are determined in the temperature range of...
The present work employs the complete energy matrices for a d8 configuration ion in a D2h symmetry ligand field at first time to study the relationship between electron paramagnetic resonance (EPR) spectra and local structure of (NiF6)4− coordination complex in Ni2+:ZnF2, NiF2, and Ni2+:MgF2 systems, respectively. The crystal field effect on the local structure of the three systems is investigated...
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