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The N,$$\hbox {N}^\prime $$ N′ -Bis(salicylidene)-2-hydroxy-phenylmethanediamine (BSHPMD) was synthesized and characterized by IR, UV-Vis and $$^{1} \hbox {H}$$ 1H NMR spectroscopic techniques. The single crystal X-ray diffraction studies reveal that the compound had a monoclinic crystal system with C2/c space group. The cation recognizing profile of the receptor BSHPMD was explored by UV-Vis and...