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A chiral sensing platform was constructed via adsorptive functionalization of ammonium persulfate doped polyaniline (APS‐DPANI) with bovine serum albumin (BSA). The novelty of this work is the construction of such chiral interface with adsorption principle. The material has been characterized by scanning electron microscope, Fourier transform infrared and X‐ray photoelectron spectroscopy, and thermogravimetric...
A composite chiral interface (BSA‐MB‐MWCNTs) was prepared from bovine serum albumin (BSA), methylene blue (MB), and multi‐walled carbon nanotubes (MWCNTs) for chiral recognition of amine enantiomers (1S, 2S)‐N,N′‐dimethyl‐1,2‐cyclohexanediamine and (1R, 2R)‐N,N′‐dimethyl‐1,2‐cyclohexanediamine. The BSA‐based composite was characterized by field emission scanning electron microscopy (FESEM) and ultraviolet–visible...
The heterogeneous enantioselective hydrogenation of α‐ketoesters catalyzed by rhodium nanoparticles (Rh NPs) in ionic liquid was studied with the stabilization and modification of cinchona alkaloids. TEM characterization showed that well‐dispersed Rh NPs of about 1.96 nm were obtained in ionic liquid. The results showed that cinchona alkaloids not only had good enantiodifferentiating ability but also...
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