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Results of research on the mechanism of delithiation of LiFe 0.75 Zn 0.25 PO 4 cathode material having olivine structure are presented. Introduction of zinc into Fe-sublattice of LiFePO 4 caused a decrease of unit cell volume, however, shrinkage of unit cell parameters a and b was accompanied by an increase of parameter c. Analysis of phase composition during delithiation...
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