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A new family of polyoxometalates-based inorganic–organic hybrid compounds, namely, [Ag4(H2O)(L)3(SiW12O40)] (1), [Zn(L)(H2O)]2[SiW12O40]·3H2O (2), [Cu(L)(H2O)]2[SiW12O40] (3), and [Cu2(L)2(HPWVI10WV2O40)]·4H2O (4), have been synthesized (L = 1,4–bis(3-(2-pyridyl)pyrazol)butane). This series of inorganic–organic hybrid compounds exhibit variable supramolecular architectures. The photodegradation of...
The metallic nanostructures with unique properties of tunable plasmon resonance and large field enhancement have been cooperated with semiconductor to construct hetero‐nanostructures for various applications. Herein, a general and facile approach to synthesize uniform dumbbell‐like gold–sulfide core–shell hetero‐nanostructures is reported. The transformation from Au nanorods (NRs) to dumbbell‐like...
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