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While the hydrogen atom abstraction (HAA) from C(sp3)−H bond has been well explored, the radical‐mediated chemo‐ and regio‐selective functionalization of allenic C(sp2)−H bond via direct HAA from C(sp2)−H bond of allene remains an unsolved challenge in synthetic chemistry. This is primarily due to inherent challenges with addition of radical intermediates to allenes, regioselectivity of HAA process,...
While the hydrogen atom abstraction (HAA) from C(sp3)−H bond has been well explored, the radical‐mediated chemo‐ and regio‐selective functionalization of allenic C(sp2)−H bond via direct HAA from C(sp2)−H bond of allene remains an unsolved challenge in synthetic chemistry. This is primarily due to inherent challenges with addition of radical intermediates to allenes, regioselectivity of HAA process,...
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