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N-Heterocyclic carbene–Pd(II) complex 1 derived from proline was found to be an efficient catalyst in the Mizoroki–Heck reaction of aryl bromides and iodides performed in water. The reactions can tolerate various functional groups in the substrates and all gave the corresponding coupling products in good to high yields.
Pd(II)–N-heterocyclic carbene complexes derived from proline have been successfully synthesized in good yields and their structures have been characterized by X-ray single crystal diffraction. It was found that the substituents on the N-atom of the pyrrolidine skeleton dramatically affect on the coordination pattern of the palladium complexes. In a word, when an electron-rich group as benzyl group...
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