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The geometric parameters of the macrotricyclic CoII, NiII, CuII, and ZnII chelates with (NSSN) coordination of the donor centers of the ligand, which are formed by complex formation between the metal ions, hydrazinomethane thioamide H2N-HN-C(=S)-NH2, and butane-2,3-dione Me-C(=O)-C(=O)-Me in aqueous solutions and gelatin-immobilized matrix implants, were calculated using the DFT B3LYP hybrid method...
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