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A nearly‐30‐year‐old unanswered synthetic puzzle, astellatol, has been solved in an enantiospecific manner. The highly congested pentacyclic skeleton of this rare sesterterpenoid, which possesses a unique bicyclo[4.1.1]octane motif, ten stereocenters, a cyclobutane that contains two quaternary centers, an exo‐methylene group, and a sterically encumbered isopropyl trans‐hydrindane motif, makes astellatol...
Der Chinesische Scherenschnitt …… hat eine lange Tradition, auch als Dekoration von Türen und Fenstern beim Neujahrsfest. Das chinesische Schriftzeichen 福 steht für Glück, 春 für Frühling. Vor diesem Hintergrund präsentieren J. Xu et al. in ihrer Zuschrift auf S. 3444 die erste enantiospezifische Synthese für Astellatol, das drei Jahrzehnte lang eine Herausforderung darstellte.
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