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This paper attempts to describe a plausible scheme of reaction(s) that governs the electrodeposition of boron from melts containing KCl, KF and KBF 4 (at 1073K). Four different stoichiometric equations were formulated based on the existence of various chloride–fluoride complexes derived from the fluoroborate anion. During the electrolysis all these chloride–fluoride complex anions of boron...
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