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Styrene-butadiene-styrene (SBS) block copolymer exposed to UV radiation in the presence of unimolecular and bimolecular photoinitiators yields a crosslinked polymer. When 2,2-dimethoxy-2-phenylacetophenone is used as photoinitiator the photocrosslinking takes place fundamentally through the addition of the benzoyl and/or dimethoxyphenyl radicals to the double bonds (cis, trans and vinyl) of the SBS...
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