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The photochemical reaction of magnesium tetraphenyl porphyrin (MgTPP) with O 2 was studied in CH 2 Cl 2 by steady-state fluorescence, UV–vis absorption, FTIR and MALDI–TOF MS measurements. These spectra indicate that O 2 can react with MgTPP excited by irradiation, forming the stable 1:1 coordinated adduct of MgTPP–O 2 . In the adduct, the oxygen atoms of O...
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