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This paper reports an “off-to-on” fluorescence (FL) probe for sensitively and selectively detecting phosphate ions (Pi's). Fabrication of the probe was based on the competition between Pi's and tannic acid-stabilized copper nanoclusters (TA-Cu NCs) for Eu3+ binding. The addition of Eu3+ ions to TA-Cu NCs triggered the aggregation of TA-Cu NCs, which quenched the FL of TA-Cu NCs. After Pi addition,...
A simple, one-step facile route for preparation of water soluble and fluorescent Cu nanoclusters (NCs) stabilized by tannic acid (TA) is described. The as-prepared TA capped Cu NCs (TA-Cu NCs) are characterized by UV–vis spectroscopy, Fourier transform infrared (FT-IR) spectroscopy, luminescence, transmission electron microscopy (TEM), and X-ray photoelectron spectroscopy (XPS). The TA-Cu NCs show...
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