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Design of high‐performance all‐inorganic halide perovskites, especially lead‐free perovskites, is key to the broadening of its application prospects. Herein, the authors report the synthesis of ligand‐free cesium platinum (IV) bromide nanocrystals (Cs2PtBr6 NCs), a new kind of vacancy‐ordered lead‐free perovskite nanomaterial, by a facile one‐pot method. The Cs2PtBr6 NCs exhibits a narrow band gap...
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