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A new synthetic route to cis‐(CyPNP)Fe(CO)2H (CyPNP=2,5‐bis(dicyclohexylphosphinomethyl)pyrrolyl) has been developed, involving the reaction of (CyPNP)Fe(CO)2Br with NaBH4. The Fe−H bond of this iron hydride is remarkably stable to acids (e. g., HBF4 ⋅ Et2O, HCl, and CH3CO2H) and oxidants (e. g., 1,4‐benzoquinone and galvinoxyl), only leading to the protonation of the β‐pyrrolic carbon and the oxidation...