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A novel solid–solid phase‐change energy storage material was synthesized by the aqueous phase precipitation polymerization. The amphiphilic polyethylene glycol‐maleic acid monoester macromonomer (MAPEG) with a double bond and a terminal carboxyl was the side chain and the polyacrylonitrile (PAN) was a skeleton. The chemical structure and thermal properties of the graft copolymer were investigated...
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