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This minireview summarizes the current state of knowledge concerning the role of Cl− in the oxygen-evolving complex (OEC) of photosystem II (PSII). The model that proposes that Cl− is a Mn ligand is discussed in light of more recent work. Studies of Cl− specificity, stoichiometry, kinetics, and retention by extrinsic polypeptides are discussed, as are the results that fail to detect Cl− ligation to...
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