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Direct dehydrogenation of methane to produce more useful chemicals was examined using low temperature plasmas such as DBD, corona and spark discharge under the conditions of room temperature and atmospheric pressure. In spark discharge, acetylene was produced with the selectivity higher than 85% and small amount of deposited carbon. The energy efficiency in spark discharge was much higher than that...
The reaction mechanism of methane activation using non-equilibrium pulsed discharge was largely clarified from the emission spectroscopic study and experiments with higher hydrocarbons and some kinds of isotopes. The strong emission of atomic carbon and C 2 swan band system was observed as well as H Balmer series emission. This indicates that methane was highly dissociated into C and H by...
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