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The Gibbs energy of the liquid phases in the SmCl 3 –MCl (M=Na, K, Rb, Cs) systems is described by a modified quasi-chemical model. Based on measured phase equilibrium data and experimental thermochemical properties of these binary systems, a set of thermodynamic functions has been optimized by using the CALPHAD technique. The calculations based on the obtained descriptions show good agreement...
The binary phase diagrams of the NdCl 3 –MCl (M=Li, Na, K, Rb, Cs) systems were studied using the CALPHAD technique. For describing the Gibbs energies of the liquid phase in these systems, the new modified quasi-chemical model in the pair-approximation for short-range ordering was used. Based on measured phase equilibrium data and experimental thermochemical properties, a set of thermodynamic...
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