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The integral molar mixing enthalpy of liquid ternary Ga-Li-Zn alloys has been investigated using drop calorimetry method at different temperatures and along four intersections as follows: XLi/XZn=9/1 at 1006K, XGa/XZn=1/9 at 813K, XGa/XZn=1/1 at 1018K XGa/XZn=9/1 at 1017K. The available in the literature equations describing the excess Gibbs energy of binary Ga-Li, Ga-Zn and Li-Zn systems in the form...
The solution-reaction calorimetric method was used for the determination of the formation enthalpy of the Li 22 Si 5 intermetallic compound and the heat of the reaction of the Li-component with an acetic acid bath. The phase was prepared in a glove box with high purity argon protective atmosphere. The phase was homogenized and then analyzed by means of the X-ray diffraction technique...
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