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Catalytic epoxidation of α-H-containing olefins with air over nanosized metal oxides under mild conditions has been first reported. Nanosized Co3O4 was considerably active for the epoxidation of α-pinene and cinnamyl chloride with air at atmospheric pressure. A substrate α-pinene conversion of 70.75 mol% with an epoxide selectivity of 87.68% was achieved at 363 K over Co3O4. Once Co3O4 was further...
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